Schrödinger's Equation — Question 2

Section 38-6 · Physics pages 6354–6355

Question 2 A real traveling sinusoid fails the time-dependent quantum equation In a free region, compare Ψ1 = A cos(kx −ωt) with Ψ2 = A cos(kx)e−iωt, where A is real, k > 0, and ω = ℏk2/(2m) > 0. Use iℏ∂tΨ = −(ℏ2/2m)∂2 xΨ + V Ψ. x ψ(x) = A cos kx Schematic; labels, not drawing lengths, specify the data. (a) Test Ψ1 by differentiating both sides. (b) Test Ψ2 and determine whether its probability density moves.
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Question 2 - Solution A real traveling sinusoid fails the time-dependent quantum equation x ψ(x) = A cos kx (a) Method and calculation iℏ∂tΨ1 = iℏωA sin(kx −ωt). −ℏ2 2m∂2 xΨ1 = ℏ2k2 2m A cos(kx −ωt) ⇒ Ψ1 fails . (b) Interpretation and further calculation iℏ∂tΨ2 = ℏωΨ2 = ℏ2k2 2m Ψ2 ⇒ Ψ2 satisfies . |Ψ2|2 = A2 cos2(kx), ∂t|Ψ2|2 = 0 . Physical check Taking only the real part of a complex solution is not generally allowed for this equation. The stationary standing wave combines opposite momenta at the same energy.

Question 2

A real traveling sinusoid fails the time-dependent quantum equation

In a free region, compare Ψ1=Acos⁡(kx−ωt)\Psi_1=A\cos(kx-\omega t) with Ψ2=Acos⁡(kx)e−iωt\Psi_2=A\cos(kx)e^{-i\omega t}, where A is real, k>0k>0, and ω=ℏk2/(2m)>0\omega=\hbar k^2/(2m)>0. Use iℏ∂tΨ=−(ℏ2/2m)∂x2Ψ+VΨi\hbar\partial_t\Psi=-(\hbar^2/2m)\partial_x^2\Psi+V\Psi.

Diagram shown in the original SVG worksheet.

  1. Test Ψ1\Psi_1 by differentiating both sides.

  2. Test Ψ2\Psi_2 and determine whether its probability density moves.

Question 2 - Solution

A real traveling sinusoid fails the time-dependent quantum equation

Diagram shown in the original SVG worksheet.

(a) Method and calculation

iℏ∂tΨ1=iℏωAsin⁡(kx−ωt).i\hbar\partial_t\Psi_1=i\hbar\omega A\sin(kx-\omega t).−ℏ22m∂x2Ψ1=ℏ2k22mAcos⁡(kx−ωt)⇒Ψ1 fails.-\frac{\hbar^2}{2m}\partial_x^2\Psi_1=\frac{\hbar^2k^2}{2m}A\cos(kx-\omega t)\quad\Rightarrow\quad\boxed{\Psi_1\text{ fails}}.

(b) Interpretation and further calculation

iℏ∂tΨ2=ℏωΨ2=ℏ2k22mΨ2⇒Ψ2 satisfies.i\hbar\partial_t\Psi_2=\hbar\omega\Psi_2=\frac{\hbar^2k^2}{2m}\Psi_2\quad\Rightarrow\quad\boxed{\Psi_2\text{ satisfies}}.|Ψ2|2=A2cos⁡2(kx),∂t|Ψ2|2=0.\boxed{|\Psi_2|^2=A^2\cos^2(kx),\quad\partial_t|\Psi_2|^2=0}.

Physical check

Taking only the real part of a complex solution is not generally allowed for this equation. The stationary standing wave combines opposite momenta at the same energy.